High- to low-latitude teleconnections during glacial terminations associated with ENSO-like variability

Long-term changes in ENSO-like dynamics during deglaciations are linked to southern high-latitude regions through atmospheric and oceanic teleconnection mechanisms

Nitrogen isotopic evidence for deglacial changes in nutrient supply in the eastern equatorial Pacific

The Eastern Equatorial Pacific (EEP) is a high nutrientâ "low chlorophyll region of the ocean. Downcore nitrogen isotope records from the EEP have been previously interpreted as a direct reflection of changes in nutrient consumption. However, the observed changes in sedimentary δ15N since the last glacial maximum have no coherent relationship with export productivity or an inferred variation in the iron-to-nitrate ratio of the surface waters. Rather, downcore N isotope records in the EEP strongly resemble changes in the extent of water column denitrification as recorded in nearby sedimentary δ15N records along the western margin of the Americas. This similarity is attributed to the overprinting of the N isotopic composition of nitrate in the EEP through the advection of nitrate westward from the margins in the subsurface. A local nitrogen isotope record of changes in the degree of nutrient consumption is extracted from the bulk sedimentary record by subtracting two different sedimentary δ15N records of denitrification changes from two new EEP δ15N records (TR163-22 and ODP Site 1240). The denitrification records used are from 1) the Central American margin (ODP Site 1242) and 2) the South American margin (GeoB7139-2). The degree of consumption in the surface waters declines rapidly from elevated values during the last glacial maximum to a pair of minima around 15 and 11â "13 ka, and finally it increases into the Holocene. The derived EEP nitrogen isotope record indicates that the regional peak in export productivity occurred when the supply of nutrients exceeded the apparently high demand. The influx of nutrients during the deglaciation is attributed to the resumption of intense overturning in the Southern Ocean and the release of sequestered CO2 and nutrient-rich, O2 poor waters from the deep ocean. This has important implications for understanding the glacial-interglacial scale variation in intermediate water suboxia and water column denitrification

Entrevista: Gabriel Careaga

Se reproducen las entrevistas que se hicieron a distintos intelectuales (Rodolfo Stavenhagen, Jorge Sánchez Azcona, Gabriel Careaga, Carlos Sirvent y Cristina Puga) cuando fungieron como responsables de la Revista Mexicana de Ciencias Políticas y Sociales. Se comentan diversos tópicos relacionados con la revista desde sus inicios: los artículos, las corrientes teóricas, las perspectivas, etcétera

Entrevista: Cristina Puga

Se reproducen las entrevistas que se hicieron a distintos intelectuales (Rodolfo Stavenhagen, Jorge Sánchez Azcona, Gabriel Careaga, Carlos Sirvent y Cristina Puga) cuando fungieron como responsables de la Revista Mexicana de Ciencias Políticas y Sociales. Se comentan diversos tópicos relacionados con la revista desde sus inicios: los artículos, las corrientes teóricas, las perspectivas, etcétera

Entrevista: Jorge Sánchez Azcona

Se reproducen las entrevistas que se hicieron a distintos intelectuales (Rodolfo Stavenhagen, Jorge Sánchez Azcona, Gabriel Careaga, Carlos Sirvent y Cristina Puga) cuando fungieron como responsables de la Revista Mexicana de Ciencias Políticas y Sociales. Se comentan diversos tópicos relacionados con la revista desde sus inicios: los artículos, las corrientes teóricas, las perspectivas, etcétera

Entrevista: Rodolfo Stavenhagen

Se reproducen las entrevistas que se hicieron a distintos intelectuales (Rodolfo Stavenhagen, Jorge Sánchez Azcona, Gabriel Careaga, Carlos Sirvent y Cristina Puga) cuando fungieron como responsables de la Revista Mexicana de Ciencias Políticas y Sociales. Se comentan diversos tópicos relacionados con la revista desde sus inicios: los artículos, las corrientes teóricas, las perspectivas, etcétera

Identification and removal of Mn-Mg-rich contaminant phases in foraminiferal tests: Implications for Mg/Ca past temperature reconstructions

The geochemical composition of foraminifera shells from an Ocean Drilling Program site in the Panama Basin has been analyzed by several analytical techniques (LA-ICP-MS, ICP-MS, XRD, SEM, EDX) in order to identify and evaluate the occurrence of contaminant phases which may bias paleoenvironmental reconstructions. LA-ICP-MS results on uncleaned tests indicate the presence of Mn-Mg-rich contaminant phases at the inner surfaces of the foraminiferal shells (which have Mn/Ca ratios up to 400 mmol mol-1 and Mg/Ca ratios up to 50 mmol mol-1). We have rigorously assessed the ability of different cleaning protocols to remove these contaminant phases and have obtained satisfactory results only when a reductive step is included. The analysis of cleaning residuals collected after each of the different cleaning steps applied reveals that high Mn values are associated with at least two different contaminant phases, of which only one is linked to high Mg values. XRD analysis further reveals that the Mn-Mg-rich phase is the Ca-Mn-Mg carbonate kutnahorite (Ca(Mn, Mg)(CO3)2). Our results demonstrate that the presence of kutnahorite-like minerals can bias Mg/Ca ratios toward higher values (by 7-36%) and lead to significant overestimation of past seawater temperatures (by 0.9 up to 6.2°C, in the case of these Panama Basin samples)

Holocene hydrography evolution in the Alboran Sea: a multi-record and multiproxy comparison

A new high-resolution deglacial and Holocene sea surface temperature (SST) reconstruction is presented for the Alboran Sea (western Mediterranean), based on Mg=Ca ratios measured in the planktonic foraminifera Globigerina bulloides. This new record is evaluated by comparison with other Mg=Ca SST records and previously published alkenone SST reconstructions from the same region for both the Holocene and glacial periods. In all cases there is a high degree of coherence between the different Mg=Ca SST records but strong discrepancies when compared to the alkenone SST records. We argue that these discrepancies are due to differences in the proxy response during deglaciation which we hypothesize to reflect a resilience strategy of G. bulloides, changing its main growth season, and consequently Mg=Ca records a shorter deglacial warming than alkenones. In contrast, short-term Holocene SST variability is larger in the Mg=Ca SST than in the alkenone SST records. We propose that the larger Mg=Ca SST variability is a result of spring temperatures variability, while the smoothed alkenone SST variability represents averaged annual temperatures. The Mg=Ca SST record differentiates the Holocene into three periods: (1) the warmest SST values occurred during the Early Holocene (11.7-9 cal. kyr BP), (2) a continuous cooling trend occurred during the Middle Holocene that culminated in the coldest Holocene SST having a double cold peak structure centred at around 4.2 cal. kyr BP, and (3) the Late Holocene (4.2 cal. kyr BP to present) did not follow any clear cooling/warming trend although millennial-scale oscillations were enhanced. This SST evolution is discussed in the context of the changing properties in the Atlantic inflow water associated with North Atlantic circulation conditions and also with local hydrographical and atmospheric changes. We propose that a tight link between North Atlantic circulation patterns and the inflow of surface waters into the Mediterranean played a major role in controlling Holocene climatic variability of this region

A User‐Friendly Workbook to Facilitate Rapid and Accurate Rare Earth Element Analyses by ICP‐MS for Multispiked Samples

The rare earth elements (REEs) are widely used as geochemical tracers in the earth, planetary, and ocean sciences. Inductively coupled plasma‐mass spectrometry (ICP‐MS) has become the method of choice to analyze REE concentrations because it can rapidly measure the entire REE spectrum at the same time. This Technical Report presents a user‐friendly "REE Calculation Workbook" in Microsoft Excel to be used for calculating REE abundances in samples equilibrated with a multielement REE spike. This Workbook can be conveniently used to calculate REE concentrations in natural samples for spiked and unspiked elements measured by ICP‐MS. For the spiked elements, their concentrations are calculated using isotope dilution equations. Using these spiked elements as references, concentrations of the four mono‐isotopic REE elements, and other REE elements that are treated as mono‐isotopic elements (in our case, La and Lu), can be calculated. The REE Workbook can be easily set up for use with different REE spikes. Evaluation of our analytical quality using a quadrupole ICP‐MS on 10‐ml‐sized seawater samples shows that our analyses are comparable to high‐precision thermal ionization mass spectrometry (TIMS) studies, with much less time spent processing and analyzing, and with the added advantages of determining mono‐isotopic elements. An important result is the clear demonstration of enrichments in Gd and Er compared to neighboring elements in seawater samples. In addition, we compare and evaluate commonly used reference standards BCR‐1, Post‐Archean Australian Shale (PAAS), and North American Shale Composite (NASC)

Rapid changes in meridional advection of Southern Ocean intermediate waters to the tropical Pacific during the last 30 kyr

The Southern Ocean is increasingly recognized as a key player in the general ocean thermohaline circulation and the global climate system during glacial–interglacial transitions. In particular, the advection of Southern Ocean intermediate waters (SOIW), like Antarctic Intermediate Water and Sub-Antarctic Mode Water, to the Eastern Equatorial Pacific (EEP), through a so-called “oceanic tunnelling” mechanism, is an important means for rapid transfer of climatic signals (such as heat, fresh water, salt, and chemical species) from high-to-low latitudes. However, information on how intermediate water advection rates changed in the past, and particularly during deglaciations, is fragmentary. We present new results for Nd isotopes (εNd) in cleaned foraminifera shells (Neogloboquadrina dutertrei) for the last 30 kyr at ODP Site 1240 in the EEP. N. dutertrei preferentially dwells in the lower thermocline, at the core of the Equatorial Undercurrent (EUC), and the εNd variability over time provides a record of the changes in the εNd of the EUC. Through mixing models we show that the EUC record is primarily controlled by changes in the volume transport of intermediate waters and not by Southern Ocean εNd changes. Southern Ocean signals in the EUC are stronger during colder intervals (Younger Dryas, last glacial maximum and Heinrich stadials 1 and 2), in agreement with tropical Atlantic intermediate water records. In addition, covariations between N. dutertrei δ13C, molecular biomarkers, and diatom productivity at Site 1240 confirm the intermediate water route as an important mechanism for the transfer of climate signals from high-to-low latitudes. Changes in the SOIW chemistry during the deglaciation are likely linked to the upwelling of ‘old’ deep waters in the Southern Ocean and subsequent export as intermediate waters, which are coeval with the atmospheric CO2 rise. Moreover, a comparison of multiple proxy records for the last 30 kyr indicates a latitudinal shift and/or a change in the convection depth of intermediate waters in the Southern Ocean prior to the onset of the deglaciation